If you keep turning on Sticky Keys by mistake, you can turn Sticky Keys off and disable the Windows shortcut altogether.
It might be possible to disable Bixby entirely on your Samsung phone, depending upon which model you own.
When I am in a game and just tap the Windows key, it minimizes my game, then switches to the desktop. That annoys the hell out of me. I do not want to disable ALL Windows key combos, I use them a lot, ...
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